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Anti-wear
Table of Contents
Physical
& Chemical Properties
Anti-wear additives are those which reduce or control wear. They form
organic, metallo-organic, or metal salt films on the surface. Sliding
or rolling occurs on top of, or within, the films thus reducing metal-to-metal
contact. Anti-wear additives only reduce the rate of wear, which still
occurs, but without a catastrophic failure. The films are sacrificed
so that the wear fragments in the oil are primarily the film material.
Anti-wear performance is measured on numerous bench lubricant testers
operating under moderate conditions, where the volume or weight of
material removed is measured.
An example is the 4-ball wear test. Also, the pin-on-disk apparatus
is used and run under conditions described in ASTM G 99-90. The types
of anti-wear additives are zinc dialkyldithiophosphates (ZDDP), carbamates,
organic phosphates such as tricresyl phosphates, organic phosphates
and chlorine compounds. The most common anti-wear additive is ZDDP,
which decomposes to deposit metallo-organic species, zinc sulfide
or zinc phosphate, or reacts with the steel surface to form iron sulfide
or iron phosphate. Operating conditions control the specific film
material.
For more information call 1-888-HERGUTH (437-4884) |
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